Volcanic Islands
EJECTED GRANITIC FRAGMENTS.
In the neighbourhood of Green Mountain, fragments of extraneous rock are not unfrequently found embedded in the midst of masses of scoriae. Lieutenant Evans, to whose kindness I am indebted for much information, gave me several specimens, and I found others myself. They nearly all have a granitic structure, are brittle, harsh to the touch, and apparently of altered colours.
FIRST, a white syenite, streaked and mottled with red; it consists of well- crystallised feldspar, numerous grains of quartz, and brilliant, though small, crystals of hornblende. The feldspar and hornblende in this and the succeeding cases have been determined by the reflecting goniometer, and the quartz by its action under the blowpipe. The feldspar in these ejected fragments, like the glassy kind in the trachyte, is from its cleavage a potash-feldspar.
SECONDLY, a brick-red mass of feldspar, quartz, and small dark patches of a decayed mineral; one minute particle of which I was able to ascertain, by its cleavage, to be hornblende.
THIRDLY, a mass of confusedly crystallised white feldspar, with little nests of a dark-coloured mineral, often carious, externally rounded, having a glossy fracture, but no distinct cleavage: from comparison with the second specimen, I have no doubt that it is fused hornblende.
FOURTHLY, a rock, which at first appears a simple aggregation of distinct and large-sized crystals of dusty-coloured Labrador feldspar (Professor Miller has been so kind as to examine this mineral. He obtained two good cleavages of 86 degrees 30 minutes and 86 degrees 50 minutes. The mean of several, which I made, was 86 degrees 30 minutes. Professor Miller states that these crystals, when reduced to a fine powder, are soluble in hydrochloric acid, leaving some undissolved silex behind; the addition of oxalate of ammonia gives a copious precipitate of lime. He further remarks, that according to Von Kobell, anorthite (a mineral occurring in the ejected fragments at Mount Somma) is always white and transparent, so that if this be the case, these crystals from Ascension must be considered as Labrador feldspar. Professor Miller adds, that he has seen an account, in Erdmann's "Journal fur tecnische Chemie," of a mineral ejected from a volcano which had the external characters of Labrador feldspar, but differed in the analysis from that given by mineralogists of this mineral: the author attributed this difference to an error in the analysis of Labrador feldspar, which is very old.); but in their interstices there is some white granular feldspar, abundant scales of mica, a little altered hornblende, and, as I believe, no quartz. I have described these fragments in detail, because it is rare to find granitic rocks ejected from volcanoes with their MINERALS UNCHANGED, as is the case with the first specimen, and partially with the second. (Daubeny, in his work on Volcanoes page 386, remarks that this is the case; and Humboldt, in his "Personal Narrative" volume 1 page 236, says "In general, the masses of known primitive rocks, I mean those which perfectly resemble our granites, gneiss, and mica-slate, are very rare in lavas: the substances we generally denote by the name of granite, thrown out by Vesuvius, are mixtures of nepheline, mica, and pyroxene.") One other large fragment, found in another spot, is deserving of notice; it is a conglomerate, containing small fragments of granitic, cellular, and jaspery rocks, and of hornstone porphyries, embedded in a base of wacke, threaded by numerous thin layers of a concretionary pitchstone passing into obsidian. These layers are parallel, slightly tortuous, and short; they thin out at their ends, and resemble in form the layers of quartz in gneiss. It is probable that these small embedded fragments were not separately ejected, but were entangled in a fluid volcanic rock, allied to obsidian; and we shall presently see that several varieties of this latter series of rock assume a laminated structure.
TRACHYTIC SERIES OF ROCKS.
Those occupy the more elevated and central, and likewise the south-eastern, parts of the island. The trachyte is generally of a pale brown colour, stained with small darker patches; it contains broken and bent crystals of glassy feldspar, grains of specular iron, and black microscopical points, which latter, from being easily fused, and then becoming magnetic, I presume are hornblende. The greater number of the hills, however, are composed of a quite white, friable stone, appearing like a trachytic tuff. Obsidian, hornstone, and several kinds of laminated feldspathic rocks, are associated with the trachyte. There is no distinct stratification; nor could I distinguish a crateriform structure in any of the hills of this series. Considerable dislocations have taken place; and many fissures in these rocks are yet left open, or are only partially filled with loose fragments. Within the space (This space is nearly included by a line sweeping round Green Mountain, and joining the hills, called the Weather Port Signal, Holyhead, and that denominated (improperly in a geological sense) "the Crater of an old volcano."), mainly formed of trachyte, some basaltic streams have burst forth; and not far from the summit of Green Mountain, there is one stream of quite black, vesicular basalt, containing minute crystals of glassy feldspar, which have a rounded appearance.
The soft white stone above mentioned is remarkable from its singular resemblance, when viewed in mass, to a sedimentary tuff: it was long before I could persuade myself that such was not its origin; and other geologists have been perplexed by closely similar formations in trachytic regions. In two cases, this white earthy stone formed isolated hills; in a third, it was associated with columnar and laminated trachyte; but I was unable to trace an actual junction. It contains numerous crystals of glassy feldspar and black microscopical specks, and is marked with small darker patches, exactly as in the surrounding trachyte. Its basis, however, when viewed under the microscope, is generally quite earthy; but sometimes it exhibits a decidedly crystalline structure. On the hill marked "Crater of an old volcano," it passes into a pale greenish-grey variety, differing only in its colour, and in not being so earthy; the passage was in one case effected insensibly; in another, it was formed by numerous, rounded and angular, masses of the greenish variety, being embedded in the white variety; – in this latter case, the appearance was very much like that of a sedimentary deposit, torn up and abraded during the deposition of a subsequent stratum. Both these varieties are traversed by innumerable tortuous veins (presently to be described), which are totally unlike injected dikes, or indeed any other veins which I have ever seen. Both varieties include a few scattered fragments, large and small, of dark- coloured scoriaceous rocks, the cells of some of which are partially filled with the white earthy stone; they likewise include some huge blocks of a cellular porphyry. (The porphyry is dark coloured; it contains numerous, often fractured, crystals of white opaque feldspar, also decomposing crystals of oxide of iron; its vesicles include masses of delicate, hair- like, crystals, apparently of analcime.) These fragments project from the weathered surface, and perfectly resemble fragments embedded in a true sedimentary tuff. But as it is known that extraneous fragments of cellular rock are sometimes included in columnar trachyte, in phonolite (D'Aubuisson "Traite de Geognosie" tome 2 page 548.), and in other compact lavas, this circumstance is not any real argument for the sedimentary origin of the white earthy stone. (Dr. Daubeny on Volcanoes, page 180 seems to have been led to believe that certain trachytic formations of Ischia and of the Puy de Dome, which closely resemble these of Ascension, were of sedimentary origin, chiefly from the frequent presence in them "of scoriform portions, different in colour from the matrix." Dr. Daubeny adds, that on the other hand, Brocchi, and other eminent geologists, have considered these beds as earthy varieties of trachyte; he considers the subject deserving of further attention.) The insensible passage of the greenish variety into the white one, and likewise the more abrupt passage by fragments of the former being embedded in the latter, might result from slight differences in the composition of the same mass of molten stone, and from the abrading action of one such part still fluid on another part already solidified. The curiously formed veins have, I believe, been formed by siliceous matter being subsequently segregated. But my chief reason for believing that these soft earthy stones, with their extraneous fragments, are not of sedimentary origin, is the extreme improbability of crystals of feldspar, black microscopical specks, and small stains of a darker colour occurring in the same proportional numbers in an aqueous deposit, and in masses of solid trachyte. Moreover, as I have remarked, the microscope occasionally reveals a crystalline structure in the apparently earthy basis. On the other hand, the partial decomposition of such great masses of trachyte, forming whole mountains, is undoubtedly a circumstance of not easy explanation.
VEINS IN THE EARTHY TRACHYTIC MASSES.
These veins are extraordinarily numerous, intersecting in the most complicated manner both coloured varieties of the earthy trachyte: they are best seen on the flanks of the "Crater of the old volcano." They contain crystals of glassy feldspar, black microscopical specks and little dark stains, precisely as in the surrounding rock; but the basis is very different, being exceedingly hard, compact, somewhat brittle, and of rather less easy fusibility. The veins vary much, and suddenly, from the tenth of an inch to one inch in thickness; they often thin out, not only on their edges, but in their central parts, thus leaving round, irregular apertures; their surfaces are rugged. They are inclined at every possible angle with the horizon, or are horizontal; they are generally curvilinear, and often interbranch one with another. From their hardness they withstand weathering, and projecting two or three feet above the ground, they occasionally extend some yards in length; these plate-like veins, when struck, emit a sound, almost like that of a drum, and they may be distinctly seen to vibrate; their fragments, which are strewed on the ground, clatter like pieces of iron when knocked against each other. They often assume the most singular forms; I saw a pedestal of the earthy trachyte, covered by a hemispherical portion of a vein, like a great umbrella, sufficiently large to shelter two persons. I have never met with, or seen described, any veins like these; but in form they resemble the ferruginous seams, due to some process of segregation, occurring not uncommonly in sandstones, – for instance, in the New Red sandstone of England. Numerous veins of jasper and of siliceous sinter, occurring on the summit of this same hill, show that there has been some abundant source of silica, and as these plate-like veins differ from the trachyte only in their greater hardness, brittleness, and less easy fusibility, it appears probable that their origin is due to the segregation or infiltration of siliceous matter, in the same manner as happens with the oxides of iron in many sedimentary rocks.
SILICEOUS SINTER AND JASPER.
The siliceous sinter is either quite white, of little specific gravity, and with a somewhat pearly fracture, passing into pinkish pearl quartz; or it is yellowish white, with a harsh fracture, and it then contains an earthy powder in small cavities. Both varieties occur, either in large irregular masses in the altered trachyte, or in seams included in broad, vertical, tortuous, irregular veins of a compact, harsh stone of a dull red colour, appearing like a sandstone. This stone, however, is only altered trachyte; and a nearly similar variety, but often honeycombed, sometimes adheres to the projecting plate-like veins, described in the last paragraph. The jasper is of an ochre yellow or red colour; it occurs in large irregular masses, and sometimes in veins, both in the altered trachyte and in an associated mass of scoriaceous basalt. The cells of the scoriaceous basalt are lined or filled with fine, concentric layers of chalcedony, coated and studded with bright-red oxide of iron. In this rock, especially in the rather more compact parts, irregular angular patches of the red jasper are included, the edges of which insensibly blend into the surrounding mass; other patches occur having an intermediate character between perfect jasper and the ferruginous, decomposed, basaltic base. In these patches, and likewise in the large vein-like masses of jasper, there occur little rounded cavities, of exactly the same size and form with the air-cells, which in the scoriaceous basalt are filled and lined with layers of chalcedony. Small fragments of the jasper, examined under the microscope, seem to resemble the chalcedony with its colouring matter not separated into layers, but mingled in the siliceous paste, together with some impurities. I can understand these facts, – namely, the blending of the jasper into the semi-decomposed basalt, – its occurrence in angular patches, which clearly do not occupy pre-existing hollows in the rock, – and its containing little vesicles filled with chalcedony, like those in the scoriaceous lava, – only on the supposition that a fluid, probably the same fluid which deposited the chalcedony in the air-cells, removed in those parts where there were no cavities, the ingredients of the basaltic rock, and left in their place silica and iron, and thus produced the jasper. In some specimens of silicified wood, I have observed, that in the same manner as in the basalt, the solid parts were converted into a dark-coloured homogeneous stone, whereas the cavities formed by the larger sap-vessels (which may be compared with the air-vesicles in the basaltic lava) and other irregular hollows, apparently produced by decay, were filled with concentric layers of chalcedony; in this case, there can be little doubt that the same fluid deposited the homogeneous base and the chalcedonic layers. After these considerations, I cannot doubt but that the jasper of Ascension may be viewed as a volcanic rock silicified, in precisely the same sense as this term is applied to wood, when silicified; we are equally ignorant of the means by which every atom of wood, whilst in a perfect state, is removed and replaced by atoms of silica, as we are of the means by which the constituent parts of a volcanic rock could be thus acted on. (Beudant "Voyage en Hongrie" tome 3 pages 502, 504 describes kidney-shaped masses of jasper-opal, which either blend into the surrounding trachytic conglomerate, or are embedded in it like chalk-flints; and he compares them with the fragments of opalised wood, which are abundant in this same formation. Beudant, however, appears to have viewed the process of their formation rather as one of simple infiltration than of molecular exchange; but the presence of a concretion, wholly different from the surrounding matter, if not formed in a pre-existing hollow, clearly seems to me to require, either a molecular or mechanical displacement of the atoms, which occupied the space afterwards filled by it. The jasper-opal of Hungary passes into chalcedony, and therefore in this case, as in that of Ascension, jasper seems to be intimately related in origin with chalcedony.) I was led to the careful examination of these rocks, and to the conclusion here given, from having heard the Rev. Professor Henslow express a similar opinion, regarding the origin in trap-rocks of many chalcedonies and agates. Siliceous deposits seem to be very general, if not of universal occurrence, in partially decomposed trachytic tuffs (Beudant "Voyage Min." tome 3 page 507 enumerates cases in Hungary, Germany, Central France, Italy, Greece, and Mexico.); and as these hills, according to the view above given, consist of trachyte softened and altered in situ, the presence of free silica in this case may be added as one more instance to the list.
CONCRETIONS IN PUMICEOUS TUFF.
The hill, marked in Map 2 "Crater of an old volcano," has no claims to this appellation, which I could discover, except in being surmounted by a circular, very shallow, saucer-like summit, nearly half a mile in diameter. This hollow has been nearly filled up with many successive sheets of ashes and scoriae, of different colours, and slightly consolidated. Each successive saucer-shaped layer crops out all round the margin, forming so many rings of various colours, and giving to the hill a fantastic appearance. The outer ring is broad, and of a white colour; hence it resembles a course round which horses have been exercised, and has received the name of the Devil's Riding School, by which it is most generally known. These successive layers of ashes must have fallen over the whole surrounding country, but they have all been blown away except in this one hollow, in which probably moisture accumulated, either during an extraordinary year when rain fell, or during the storms often accompanying volcanic eruptions. One of the layers of a pinkish colour, and chiefly derived from small, decomposed fragments of pumice, is remarkable, from containing numerous concretions. These are generally spherical, from half an inch to three inches in diameter; but they are occasionally cylindrical, like those of iron-pyrites in the chalk of Europe. They consist of a very tough, compact, pale-brown stone, with a smooth and even fracture. They are divided into concentric layers by thin white partitions, resembling the external superficies; six or eight of such layers are distinctly defined near the outside; but those towards the inside generally become indistinct, and blend into a homogeneous mass. I presume that these concentric layers were formed by the shrinking of the concretion, as it became compact. The interior part is generally fissured by minute cracks or septaria, which are lined, both by black, metallic, and by other white and crystalline specks, the nature of which I was unable to ascertain. Some of the larger concretions consist of a mere spherical shell, filled with slightly consolidated ashes. The concretions contain a small proportion of carbonate of lime: a fragment placed under the blowpipe decrepitates, then whitens and fuses into a blebby enamel, but does not become caustic. The surrounding ashes do not contain any carbonate of lime; hence the concretions have probably been formed, as is so often the case, by the aggregation of this substance. I have not met with any account of similar concretions; and considering their great toughness and compactness, their occurrence in a bed, which probably has been subjected only to atmospheric moisture, is remarkable.
FORMATION OF CALCAREOUS ROCKS ON THE SEA-COAST.
On several of the sea-beaches, there are immense accumulations of small, well-rounded particles of shells and corals, of white, yellowish, and pink colours, interspersed with a few volcanic particles. At the depth of a few feet, these are found cemented together into stone, of which the softer varieties are used for building; there are other varieties, both coarse and fine-grained, too hard for this purpose: and I saw one mass divided into even layers half an inch in thickness, which were so compact that when struck with a hammer they rang like flint. It is believed by the inhabitants, that the particles become united in the course of a single year. The union is effected by calcareous matter; and in the most compact varieties, each rounded particle of shell and volcanic rock can be distinctly seen to be enveloped in a husk of pellucid carbonate of lime. Extremely few perfect shells are embedded in these agglutinated masses; and I have examined even a large fragment under a microscope, without being able to discover the least vestige of striae or other marks of external form: this shows how long each particle must have been rolled about, before its turn came to be embedded and cemented. (The eggs of the turtle being buried by the parent, sometimes become enclosed in the solid rock. Mr. Lyell has given a figure ("Principles of Geology" book 3 chapter 17) of some eggs, containing the bones of young turtles, found thus entombed.) One of the most compact varieties, when placed in acid, was entirely dissolved, with the exception of some flocculent animal matter; its specific gravity was 2.63. The specific gravity of ordinary limestone varies from 2.6 to 2.75; pure Carrara marble was found by Sir H. De la Beche to be 2.7. ("Researches in Theoretical Geology" page 12.) It is remarkable that these rocks of Ascension, formed close to the surface, should be nearly as compact as marble, which has undergone the action of heat and pressure in the plutonic regions.
The great accumulation of loose calcareous particles, lying on the beach near the Settlement, commences in the month of October, moving towards the S.W., which, as I was informed by Lieutenant Evans, is caused by a change in the prevailing direction of the currents. At this period the tidal rocks, at the S.W. end of the beach, where the calcareous sand is accumulating, and round which the currents sweep, become gradually coated with a calcareous incrustation, half an inch in thickness. It is quite white, compact, with some parts slightly spathose, and is firmly attached to the rock. After a short time it gradually disappears, being either redissolved, when the water is less charged with lime, or more probably is mechanically abraded. Lieutenant Evans has observed these facts, during the six years he has resided at Ascension. The incrustation varies in thickness in different years: in 1831 it was unusually thick. When I was there in July, there was no remnant of the incrustation; but on a point of basalt, from which the quarrymen had lately removed a mass of the calcareous freestone, the incrustation was perfectly preserved. Considering the position of the tidal-rocks, and the period at which they become coated, there can be no doubt that the movement and disturbance of the vast accumulation of calcareous particles, many of them being partially agglutinated together, cause the waves of the sea to be so highly charged with carbonate of lime, that they deposit it on the first objects against which they impinge. I have been informed by Lieutenant Holland, R.N., that this incrustation is formed on many parts of the coast, on most of which, I believe, there are likewise great masses of comminuted shells.
A FRONDESCENT CALCAREOUS INCRUSTATION.
(FIGURE 5. AN INCRUSTATION OF CALCAREOUS AND ANIMAL MATTER, coating the tidal-rocks at Ascension.)
In many respects this is a singular deposit; it coats throughout the year the tidal volcanic rocks, that project from the beaches composed of broken shells. Its general appearance is well represented in Figure 5; but the fronds or discs, of which it is composed, are generally so closely crowded together as to touch. These fronds have their sinuous edges finely crenulated, and they project over their pedestals or supports; their upper surfaces are either slightly concave, or slightly convex; they are highly polished, and of a dark grey or jet black colour; their form is irregular, generally circular, and from the tenth of an inch to one inch and a half in diameter; their thickness, or amount of their projection from the rock on which they stand, varies much, about a quarter of an inch being perhaps most usual. The fronds occasionally become more and more convex, until they pass into botryoidal masses with their summits fissured; when in this state, they are glossy and of an intense black, so as to resemble some fused metallic substance. I have shown the incrustation, both in this latter and in its ordinary state to several geologists, but not one could conjecture its origin, except that perhaps it was of volcanic nature!
The substance forming the fronds has a very compact and often almost crystalline fracture; the edges being translucent, and hard enough easily to scratch calcareous spar. Under the blowpipe it immediately becomes white, and emits a strong animal odour, like that from fresh shells. It is chiefly composed of carbonate of lime; when placed in muriatic acid it froths much, leaving a residue of sulphate of lime, and of an oxide of iron, together with a black powder, which is not soluble in heated acids. This latter substance seems to be carbonaceous, and is evidently the colouring matter. The sulphate of lime is extraneous, and occurs in distinct, excessively minute, lamellar plates, studded on the surface of the fronds, and embedded between the fine layers of which they are composed; when a fragment is heated in the blowpipe, these lamellae are immediately rendered visible. The original outline of the fronds may often be traced, either to a minute particle of shell fixed in a crevice of the rock, or to several cemented together; these first become deeply corroded, by the dissolving power of the waves, into sharp ridges, and then are coated with successive layers of the glossy, grey, calcareous incrustation. The inequalities of the primary support affect the outline of every successive layer, in the same manner as may often be seen in bezoar-stones, when an object like a nail forms the centre of aggregation. The crenulated edges, however, of the frond appear to be due to the corroding power of the surf on its own deposit, alternating with fresh depositions. On some smooth basaltic rocks on the coast of St. Jago, I found an exceedingly thin layer of brown calcareous matter, which under a lens presented a miniature likeness of the crenulated and polished fronds of Ascension; in this case a basis was not afforded by any projecting extraneous particles. Although the incrustation at Ascension is persistent throughout the year; yet from the abraded appearance of some parts, and from the fresh appearance of other parts, the whole seems to undergo a round of decay and renovation, due probably to changes in the form of the shifting beach, and consequently in the action of the breakers: hence probably it is, that the incrustation never acquires a great thickness. Considering the position of the encrusted rocks in the midst of the calcareous beach, together with its composition, I think there can be no doubt that its origin is due to the dissolution and subsequent deposition of the matter composing the rounded particles of shells and corals. (The selenite, as I have remarked is extraneous, and must have been derived from the sea-water. It is an interesting circumstance thus to find the waves of the ocean, sufficiently charged with sulphate of lime, to deposit it on the rocks, against which they dash every tide. Dr. Webster has described ("Voyage of the 'Chanticleer'" volume 2 page 319) beds of gypsum and salt, as much as two feet in thickness, left by the evaporation of the spray on the rocks on the windward coast. Beautiful stalactites of selenite, resembling in form those of carbonate of lime, are formed near these beds. Amorphous masses of gypsum, also, occur in caverns in the interior of the island; and at Cross Hill (an old crater) I saw a considerable quantity of salt oozing from a pile of scoriae. In these latter cases, the salt and gypsum appear to be volcanic products.) From this source it derives its animal matter, which is evidently the colouring principle. The nature of the deposit, in its incipient stage, can often be well seen upon a fragment of white shell, when jammed between two of the fronds; it then appears exactly like the thinnest wash of a pale grey varnish. Its darkness varies a little, but the jet blackness of some of the fronds and of the botryoidal masses seems due to the translucency of the successive grey layers. There is, however, this singular circumstance, that when deposited on the under side of ledges of rock or in fissures, it appears always to be of a pale, pearly grey colour, even when of considerable thickness: hence one is led to suppose, that an abundance of light is necessary to the development of the dark colour, in the same manner as seems to be the case with the upper and exposed surfaces of the shells of living mollusca, which are always dark, compared with their under surfaces and with the parts habitually covered by the mantle of the animal. In this circumstance, – in the immediate loss of colour and in the odour emitted under the blowpipe, – in the degree of hardness and translucency of the edges, – and in the beautiful polish of the surface (From the fact described in my "Journal of Researches" of a coating of oxide of iron, deposited by a streamlet on the rocks in its bed (like a nearly similar coating at the great cataracts of the Orinoco and Nile), becoming finely polished where the surf acts, I presume that the surf in this instance, also, is the polishing agent.), rivalling when in a fresh state that of the finest Oliva, there is a striking analogy between this inorganic incrustation and the shells of living molluscous animals. (In the section descriptive of St. Paul's Rocks, I have described a glossy, pearly substance, which coats the rocks, and an allied stalactitical incrustation from Ascension, the crust of which resembles the enamel of teeth, but is hard enough to scratch plate-glass. Both these substances contain animal matter, and seem to have been derived from water in filtering through birds' dung.) This appears to me to be an interesting physiological fact. (Mr. Horner and Sir David Brewster have described "Philosophical Transactions" 1836 page 65 a singular "artificial substance, resembling shell." It is deposited in fine, transparent, highly polished, brown- coloured laminae, possessing peculiar optical properties, on the inside of a vessel, in which cloth, first prepared with glue and then with lime, is made to revolve rapidly in water. It is much softer, more transparent, and contains more animal matter, than the natural incrustation at Ascension; but we here again see the strong tendency which carbonate of lime and animal matter evince to form a solid substance allied to shell.)
